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51.
We describe the development, implementation, and first analyses of the performance of a debris-flow warning system for the Illgraben catchment and debris fan area. The Illgraben catchment (9.5 km2), located in the Canton of Valais, Switzerland, in the Rhone River valley, is characterized by frequent and voluminous sediment transport and debris-flow activity, and is one of the most active debris-flow catchments in the Alps. It is the site of an instrumented debris-flow observation station in operation since the year 2000. The residents in Susten (municipality Leuk), tourists, and other land users, are exposed to a significant hazard. The warning system consists of four modules: community organizational planning (hazard awareness and preparedness), event detection and alerting, geomorphic catchment observation, and applied research to facilitate the development of an early warning system based on weather forecasting. The system presently provides automated alert signals near the active channel prior to (5–15 min) the arrival of a debris flow or flash flood at the uppermost frequently used channel crossing. It is intended to provide data to support decision-making for warning and evacuation, especially when unusually large debris flows are expected to leave the channel near populated areas. First-year results of the detection and alert module in comparison with the data from the independent debris-flow observation station are generally favorable. Twenty automated alerts (alarms) were issued, which triggered flashing lights and sirens at all major footpaths crossing the channel bed, for three debris flows and 16 flood flows. Only one false alarm was issued. The major difficulty we encountered is related to the variability and complexity of the events (e.g., events consisting of multiple surges) and can be largely solved by increasing the duration of the alarm. All of the alarms for hazardous events were produced by storms with a rainfall duration and intensity larger than the threshold for debris-flow activity that was defined in an earlier study, supporting our intention to investigate the use of rainfall forecasts to increase the time available for warning and implementation of active countermeasures.  相似文献   
52.
Mass fluxes from the ground surface can play a vital role in influencing groundwater ecosystems. Rates of delivery may influence intact ecosystem composition, while fluxes of substances associated with anthropogenic activity may critically alter the functioning of associated microbial assemblages. Field-based tracing experiments offer a valuable means of understanding mass transport rates and mechanisms, particularly in complex heterogeneous epikarst systems overlying vulnerable fissured aquifers. A short-term tracer experiment monitoring solute and particle tracer concentrations after they passed through a 10-m-thick sequence of limestone, capped by a thin soil, revealed rapid travel times and variable attenuation rates for the substances employed. Results demonstrated that particle tracers have shorter average travel times and can reach the subsurface in higher concentrations and over shorter times than non-reactive solutes. High recovery rates for the bacterial tracer Ralstonia eutropha H16 contrasted strongly with those of similarly sized fluorescent polystyrene microspheres, highlighting the importance of physico-chemical surface characteristics of particle tracers. Complementary laboratory batch experiments examined the role played by organic and inorganic soil/rock surfaces on particle tracer attenuation. Findings suggest that biofilms may significantly promote transport of particulate material below ground, i.e., the delivery of allochthonous microorganisms to karst groundwater.  相似文献   
53.
The interplay of bioturbation, soil production and long-term erosion–deposition in soil and landscape co-evolution is poorly understood. Single-grain post-infrared infrared stimulated luminescence (post-IR IRSL) measurements on sand-sized grains of feldspar from the soil matrix can provide direct information on all three processes. To explore the potential of this novel method, we propose a conceptual model of how post-IR IRSL-derived burial age and fraction of surface-visiting grains change with soil depth and along a hillslope catena. We then tested this conceptual model by comparison with post-IR IRSL results for 15 samples taken at different depths within four soil profiles along a hillslope catena in the Santa Clotilde Critical Zone Observatory (southern Spain). In our work, we observed clear differences in apparent post-IR IRSL burial age distributions with depth along the catena, with younger ages and more linear age–depth structure for the hill-base profile, indicating the influence of lateral deposition processes. We noted shallower soils and truncated burial age–depth functions for the two erosional mid-slope profiles, and an exponential decline of burial age with depth for the hill-top profile. We suggest that the downslope increase in the fraction of surface-visiting grains at intermediate depths (20 cm) indicates creep to be the dominant erosion process. Our study demonstrates that single-grain feldspar luminescence signature-depth profiles provide a new way of tracing vertical and lateral soil mixing and transport processes. In addition, we propose a new objective luminescence-based criterion for mapping the soil-bedrock boundary, thus producing soil depths in better agreement with geomorphological process considerations. Our work highlights the possibilities of feldspar single grain techniques to provide quantitative insights into soil production, bioturbation and erosion–deposition. © 2019 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons Ltd.  相似文献   
54.
Construction of frequency–magnitude (F–M) relationships of debris floods and debris flows is challenging because of few direct observations, discontinuous event occurrence, loss of field evidence, the difficulty of accessing the sediment archive and the challenge of finding suitable statistical methods to analyse the dataset. Consultants often face budget limitations that prohibit application of the full gamut of absolute dating methods, stratigraphic analysis and analytical tools necessary to fully resolve the F–M legacy. In some cases, F–M curves are needed for watersheds without local information, or where obtaining this information is prohibitively expensive. For such watersheds, the F–M relationship may be estimated where several F–M curves have already been assembled in a specific region. Individual F–M curves are normalized by fan area or fan volume, then stratified by process type and geomorphic activity level. This paper describes the development of regional F–M curves for debris flows in southwestern British Columbia and debris flows and debris floods in the Bow River valley near Canmore, Alberta. We apply the regional relationships to other cases in Canada and the United States and demonstrate that the method can be globalized. The regional approach is compared to cases where detailed F–M relationships have been established by other means. Strong negative deviations from the regional debris-flow or debris-flood magnitude trends could signal inherent watershed stability, while strong positive deviations could signal extraordinary landslide processes, or suggest that the fan may be largely of paraglacial origin. We highlight some of these outlying cases and develop a method whereby the regional curves can be meaningfully adjusted, or reliance can be placed on lower or upper confidence bounds of the F–M curves. We caution against the indiscriminate use of the regionally based F–M curves, especially in watersheds where multiple geomorphic processes are active. © 2020 John Wiley & Sons, Ltd.  相似文献   
55.
Mathematical Geosciences - Laguerre mosaics have been an important modeling approach in astronomy, physics, crystallography, geology and mathematics for several decades. In materials science, they...  相似文献   
56.
57.
A stabilized enhanced strain finite element procedure for poromechanics is fully integrated with an elasto-plastic cap model to simulate the hydro-mechanical interactions of fluid-infiltrating porous rocks with associative and non-associative plastic flow. We present a quantitative analysis on how macroscopic plastic volumetric response caused by pore collapse and grain rearrangement affects the seepage of pore fluid, and vice versa. Results of finite element simulations imply that the dissipation of excess pore pressure may significantly affect the stress path and thus alter the volumetric plastic responses.  相似文献   
58.
The Bayan Har Shan, a prominent upland area in the northeastern sector of the Tibetan Plateau, hosts an extensive glacial geological record. To reconstruct its palaeoglaciology we have determined 10Be exposure ages based on 67 samples from boulders, surface pebbles, and sediment sections in conjunction with studies of the glacial geology (remote sensing and field studies) and numerical glacier modelling. Exposure ages from moraines and glacial sediments in Bayan Har Shan range from 3 ka to 129 ka, with a large disparity in exposure ages for individual sites and within the recognised four morphostratigraphical groups. The exposure age disparity cannot be explained by differences in inheritance without using unrealistic assumptions but it can be explained by differences in post-depositional shielding which produces exposure ages younger than the deglaciation age. We present a palaeoglaciological time-slice reconstruction in which the most restricted glaciation, with glaciers less than 10 km long, occurred before 40–65 ka. More extensive glaciations occurred before 60–100 ka and 95–165 ka. Maximum glaciation is poorly constrained but probably even older. The Bayan Har Shan exposure age dataset indicates that glaciers on the northeastern Tibetan Plateau have remained surprisingly restricted for at least 40 ka, including the global last glacial maximum (LGM). This case of a missing LGM is further supported by high-resolution glacier modelling experiments.  相似文献   
59.
We studied stable iron isotope fractionation during dissolution of a biotite and chlorite enriched mineral fraction from granite by HCl and 5 mM oxalic acid in a pH range of 4-5.9. Batch experiments covered a time period from 2 h to 100 days and were performed at initial potassium concentrations of 0, 0.5, and 5 mM to induce different levels of biotite exfoliation. All experiments were kept anoxic to investigate solely the dissolution step without the influence of oxidation and precipitation of secondary Fe oxyhydroxides. Oxalic acid increased the release of Fe by a factor of ∼15 compared with the HCl experiments. Addition of 0.5 mM K to initial solutions in proton-promoted dissolution decreased the release of Fe by 30-65% depending on the dissolution stage. In ligand-controlled dissolution, K reduced the Fe release only to a minor extent. All solutions of the early dissolution stages were enriched in light Fe isotopes by up to −1.4‰ in δ56Fe compared with the isotopic composition of biotite and chlorite mineral separates, which we explained by a kinetic isotope effect. In proton-promoted dissolution, early released fractions of K-enriched experiments were significantly lighter (−0.7‰ to −0.9‰) than in the initially K-free experiments. The evolution of Fe isotope ratios in solution was modeled by a linear combination of kinetic isotope effects during two independent dissolution processes attacking different crystallographic sites. In ligand-controlled dissolution, K did not influence the kinetic isotope effect and the Fe isotope composition in solution in the late dissolution stages remained slightly lighter than the bulk composition of the biotite/chlorite enriched mineral fraction. This study demonstrates that the initial Fe weathering flux should be enriched in light Fe isotopes and that Fe isotope data in combination with dissolution kinetics and stoichiometry provide new insights into dissolution mechanisms.  相似文献   
60.
In oxic environments contaminated with arsenate (As(V)), small polyhydroxycarboxylates such as citrate may impact the structure of precipitating ferrihydrite (Fh) and thus the surface speciation of As(V). In this study, ‘2-line’ Fh was precipitated from ferric nitrate solutions that were neutralized to pH 6.5 in the presence of increasing citrate concentrations and in the absence or presence of As(V). The initial citrate/Fe and As/Fe ratios were 0-50 mol% and 5 mol%, respectively. The reaction products, enriched with up to 0.32 mol citrate per mole Fe, were characterized by X-ray diffraction, transmission electron microscopy, and Fe and As K-edge X-ray absorption spectroscopy. Citrate decreased the particle size of Fh by impairing the polymerization of Fe(O,OH)6 octahedra via edge and corner linkages. In the presence of citrate and As(V), coordination numbers of Fe decreased by up to 28% relative to pure Fh. Citrate significantly reduced the static disorder of Fe-O bonds, implying a decreased octahedral distortion in Fh. Mean bond distances in Fh were not affected by citrate and remained constant within error at 1.98 Å for Fe-O, 3.03 Å for Fe-Fe1, and 3.45 Å for Fe-Fe2. Likewise, citrate had no effect on the As-Fe (3.31 Å) bond distance in As(V) coprecipitated with Fh. The As K-edge EXAFS data comply with the formation of (i) only monodentate binuclear (2C) As(V) surface complexes and (ii) combinations of 2C, monodentate mononuclear (1V), and outersphere As(V) surface complexes. Our results suggest that increasing citrate concentrations led to a decreasing 1V/2C ratio and/or that citrate increasingly impaired the formation of outersphere As(V) complexes. Moreover, citrate stabilized colloidal suspensions of Fh (pH 4.3-6.6, I ∼0.45 M) and reduced Fh formation at the expense of soluble Fe(III)-citrate complexes. At initial citrate/Fe ratios ?25 mol%, between 8% and 41% of total Fe was bound in Fe(III)-citrate complexes after Fh formation. Polynuclear Fe(III)-citrate species were found to bind As(V) via surface complexes indistinguishable by EXAFS from those of As(V) adsorbed to or coprecipitated with Fh. Our study implies that low molecular weight polyhydroxycarboxylates may enhance the mobility of As(V) in aqueous systems of high ionic strength (e.g., neutralizing acid mine drainage) by colloidal stabilization of suspended Fh particles and the formation of ternary As(V) complexes.  相似文献   
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